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Direct electrochemical defluorinative carboxylation of α-CF(3) alkenes with carbon dioxide

An unprecedented γ-carboxylation of α-CF(3) alkenes with CO(2) is reported. This approach constitutes a rare example of using electrochemical methods to achieve regioselectivity complementary to conventional metal catalysis. Accordingly, using platinum plate as both a working cathode and a nonsacrif...

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Detalles Bibliográficos
Autores principales:	Gao, Xiao-Tong, Zhang, Zheng, Wang, Xin, Tian, Jun-Song, Xie, Shi-Liang, Zhou, Feng, Zhou, Jian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162267/ https://www.ncbi.nlm.nih.gov/pubmed/34123181 http://dx.doi.org/10.1039/d0sc04091f

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