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Rhodium-catalysed tetradehydro-Diels–Alder reactions of enediynes via a rhodium-stabilized cyclic allene

Efficient methods for the synthesis of fused-aromatic rings is a critical endeavour in the creation of new pharmaceuticals and materials. A direct method for preparing these systems is the tetradehydro-Diels–Alder reaction, however this is limited by the need for harsh reaction conditions. A potenti...

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Detalles Bibliográficos
Autores principales: Thadkapally, Srinivas, Farshadfar, Kaveh, Drew, Melanie A., Richardson, Christopher, Ariafard, Alireza, Pyne, Stephen G., Hyland, Christopher J. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162385/
https://www.ncbi.nlm.nih.gov/pubmed/34094344
http://dx.doi.org/10.1039/d0sc04390g