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Orbital energy mismatch engenders high-spin ground states in heterobimetallic complexes

The spin state in heterobimetallic complexes heavily influences both reactivity and magnetism. Exerting control over spin states in main group-based heterobimetallics requires a different approach as the orbital interactions can differ substantially from that of classic coordination complexes. By de...

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Detalles Bibliográficos
Autores principales:	Coste, Scott C., Pearson, Tyler J., Altman, Alison B., Klein, Ryan A., Finney, Brian A., Hu, Michael Y., Alp, E. Ercan, Vlaisavljevich, Bess, Freedman, Danna E.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162423/ https://www.ncbi.nlm.nih.gov/pubmed/34094259 http://dx.doi.org/10.1039/d0sc03777j

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