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Seeing luminescence appear as crystals crumble. Isolation and subsequent self-association of individual [(C(6)H(11)NC)(2)Au](+) ions in crystals
Non-luminescent, isostructural crystals of [(C(6)H(11)NC)(2)Au](EF(6))·C(6)H(6) (E = As, Sb) lose benzene upon standing in air to produce green luminescent (E = As) or blue luminescent (E = Sb) powders. Previous studies have shown that the two-coordinate cation, [(C(6)H(11)NC)(2)Au](+), self-associa...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162474/ https://www.ncbi.nlm.nih.gov/pubmed/34123201 http://dx.doi.org/10.1039/d0sc03299a |