Cargando…

Combining alkali metals and zinc to harness heterometallic cooperativity in cyclic ester ring-opening polymerisation

Heterometallic cooperativity is an emerging strategy to elevate polymerisation catalyst performance. Here, we report the first heterotrimetallic Na/Zn(2) and K/Zn(2) complexes supported by a ProPhenol ligand, which deliver “best of both” in cyclic ester ring-opening polymerisation, combining the out...

Descripción completa

Detalles Bibliográficos
Autores principales:	Gruszka, Weronika, Lykkeberg, Anna, Nichol, Gary S., Shaver, Michael P., Buchard, Antoine, Garden, Jennifer A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162475/ https://www.ncbi.nlm.nih.gov/pubmed/34123205 http://dx.doi.org/10.1039/d0sc04705h

Ejemplares similares

Advances in heterometallic ring-opening (co)polymerisation catalysis
por: Gruszka, Weronika, et al.
Publicado: (2021)

Di‐Zinc–Aryl Complexes: CO(2) Insertions and Applications in Polymerisation Catalysis
por: Romain, Charles, et al.
Publicado: (2017)

Bottle-grade polyethylene furanoate from ring-opening polymerisation of cyclic oligomers
por: Rosenboom, Jan-Georg, et al.
Publicado: (2018)

Mechanistic studies on the ring-opening polymerisation of D,L-lactide with zinc guanidine complexes
por: Herres-Pawlis, S, et al.
Publicado: (2010)

Zinc and Magnesium Complexes Bearing Oxazoline-Derived Ligands and Their Application for Ring Opening Polymerization of Cyclic Esters
por: Duan, Ranlong, et al.
Publicado: (2018)

Iron(III) Half Salen Catalysts for Atom Transfer Radical and Ring-Opening Polymerizations
por: Fazekas, Eszter, et al.
Publicado: (2018)

Editorial: Advanced Catalysts in Ring-Opening Polymerization of Cyclic Esters
por: Wu, Jincai, et al.
Publicado: (2019)

Synthesis and characterization of heterometallic rings templated through alkylammonium or imidazolium cations
por: Alotaibi, Rajeh, et al.
Publicado: (2023)

Radical Ring Opening Polymerization of Cyclic Ketene Acetals Derived From d-Glucal
por: Hardy, Craig, et al.
Publicado: (2023)

Isoselective Lactide Ring Opening Polymerisation using [2]Rotaxane Catalysts
por: Lim, Jason Y. C., et al.
Publicado: (2019)

Correction: Synthesis and characterization of heterometallic rings templated through alkylammonium or imidazolium cations
por: Alotaibi, Rajeh, et al.
Publicado: (2023)

A prochelator peptide designed to use heterometallic cooperativity to enhance metal ion affinity
por: Alies, Bruno, et al.
Publicado: (2015)

Role of torsional strain in the ring-opening polymerisation of low strain [n]nickelocenophanes
por: Musgrave, Rebecca A., et al.
Publicado: (2019)

Understanding the influence of alkali cations and halogen anions on the cooperativity of cyclic hydrogen‐bonded rosettes in supramolecular stacks
por: Petelski, Andre Nicolai, et al.
Publicado: (2022)

Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of rac-lactide
por: Jones, Matthew D., et al.
Publicado: (2015)

Monomeric Ti(IV) homopiperazine complexes and their exploitation for the ring opening polymerisation of rac-lactide
por: Hancock, Stuart L, et al.
Publicado: (2013)

Divergent Catalytic Strategies for the Cis/Trans Stereoselective Ring-Opening Polymerization of a Dual Cyclic Carbonate/Olefin Monomer
por: McGuire, Thomas M., et al.
Publicado: (2019)

Exploring Oxidation State-Dependent Selectivity in Polymerization of Cyclic Esters and Carbonates with Zinc(II) Complexes
por: Abubekerov, Mark, et al.
Publicado: (2018)

Uranium rhodium bonding in heterometallic complexes
por: Hlina, J. A., et al.
Publicado: (2017)

Lithium calix[4]arenes: structural studies and use in the ring opening polymerization of cyclic esters
por: Santoro, Orlando, et al.
Publicado: (2021)

Aluminium complexes containing indolyl-phenolate ligands as catalysts for ring-opening polymerization of cyclic esters
por: Chen, Chi-Tien, et al.
Publicado: (2022)

Macrocyclic poly(p-phenylenevinylene)s by ring expansion metathesis polymerisation and their characterisation by single-molecule spectroscopy
por: Lidster, Benjamin John, et al.
Publicado: (2018)

Direct valorisation of waste cocoa butter triglycerides via catalytic epoxidation, ring‐opening and polymerisation
por: Plaza, Dorota D, et al.
Publicado: (2017)

Ring opening polymerisation of ɛ-caprolactone with novel microwave magnetic heating and cyto-compatible catalyst
por: Wang, Kaiyang, et al.
Publicado: (2023)

Nanorings with copper(ii) and zinc(ii) centers: forcing copper porphyrins to bind axial ligands in heterometallated oligomers
por: Cremers, Jonathan, et al.
Publicado: (2016)

Implementing Mesoporosity in Zeolitic Imidazolate Frameworks through Clip-Off Chemistry in Heterometallic Iron–Zinc ZIF-8
por: León-Alcaide, Luis, et al.
Publicado: (2023)

Heterodinuclear zinc and magnesium catalysts for epoxide/CO(2) ring opening copolymerizations
por: Trott, Gemma, et al.
Publicado: (2019)

Heterodinuclear zinc and magnesium catalysts for epoxide/CO(2) ring opening copolymerizations
por: Trott, Gemma, et al.
Publicado: (2019)

Bioinspired crowding directs supramolecular polymerisation
por: Bäumer, Nils, et al.
Publicado: (2023)

Single molecule magnets of cobalt and zinc homo- and heterometallic coordination polymers prepared by a one-step synthetic procedure
por: Portolés-Gil, Núria, et al.
Publicado: (2020)

Coordination Ring-Opening Polymerization of Cyclic Esters: A Critical Overview of DFT Modeling and Visualization of the Reaction Mechanisms
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Total Synthesis of Marine Alkaloids Motuporamines A and B via Ring Expansion of Cyclic β-Keto Esters
por: Song, Zi-Jie, et al.
Publicado: (2020)

Synthesis of Poly(Lactic Acid-co-Glycolic Acid) Copolymers with High Glycolide Ratio by Ring-Opening Polymerisation
por: Little, Alastair, et al.
Publicado: (2021)

Block Copolymers Based on Ethylene and Methacrylates Using a Combination of Catalytic Chain Transfer Polymerisation (CCTP) and Radical Polymerisation
por: Baffie, Florian, et al.
Publicado: (2021)

Poly(ester-anhydrides) Derived from Esters of Hydroxy Acid and Cyclic Anhydrides
por: Arun, Yuvaraj, et al.
Publicado: (2022)

Lanthanide Photoluminescence in Heterometallic Polycyanidometallate-Based Coordination Networks
por: Chorazy, Szymon, et al.
Publicado: (2017)

Heterometallic multinuclear nodes directing MOF electronic behavior
por: Ejegbavwo, Otega A., et al.
Publicado: (2020)

Heterometallic nanomaterials: activity modulation, sensing, imaging and therapy
por: Li, Shan-Shan, et al.
Publicado: (2022)

Actin polymerisation at the cytoplasmic face of eukaryotic nuclei
por: Münter, Sylvia, et al.
Publicado: (2006)

Polymerisation‐Induced Self‐Assembly of Graft Copolymers
por: Häkkinen, Satu, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_ceeeut9qruv0ok99haapoqc3co