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Crystal structure and metallization mechanism of the π-radical metal TED

Radical electrons tend to localize on individual molecules, resulting in an insulating (Mott–Hubbard) bandgap in the solid state. Herein, we report the crystal structure and intrinsic electronic properties of the first single crystal of a π-radical metal, tetrathiafulvalene-extended dicarboxylate (T...

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Detalles Bibliográficos
Autores principales:	Kobayashi, Yuka, Hirata, Kazuto, Hood, Samantha N., Yang, Hui, Walsh, Aron, Matsushita, Yoshitaka, Ishioka, Kunie
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162741/ https://www.ncbi.nlm.nih.gov/pubmed/34123200 http://dx.doi.org/10.1039/d0sc03521a

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