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Decarbonylative ether dissection by iridium pincer complexes

A unique chain-rupturing transformation that converts an ether functionality into two hydrocarbyl units and carbon monoxide is reported, mediated by iridium(i) complexes supported by aminophenylphosphinite (NCOP) pincer ligands. The decarbonylation, which involves the cleavage of one C–C bond, one C...

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Detalles Bibliográficos
Autores principales:	Yoo, Changho, Dodge, Henry M., Farquhar, Alexandra H., Gardner, Kristen E., Miller, Alexander J. M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162749/ https://www.ncbi.nlm.nih.gov/pubmed/34123222 http://dx.doi.org/10.1039/d0sc03736b

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