Cargando…

Cobalt-catalyzed intramolecular decarbonylative coupling of acylindoles and diarylketones through the cleavage of C–C bonds

We report here cobalt–N-heterocyclic carbene catalytic systems for the intramolecular decarbonylative coupling through the chelation-assisted C–C bond cleavage of acylindoles and diarylketones. The reaction tolerates a wide range of functional groups such as alkyl, aryl, and heteroaryl groups, givin...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yu, Tian-Yang, Xu, Wen-Hua, Lu, Hong, Wei, Hao
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162806/ https://www.ncbi.nlm.nih.gov/pubmed/34094442 http://dx.doi.org/10.1039/d0sc04326e

Ejemplares similares

Palladium-catalyzed decarbonylative Suzuki–Miyaura cross-coupling of amides by carbon–nitrogen bond activation
por: Zhou, Tongliang, et al.
Publicado: (2019)

Nickel-catalyzed decarbonylation of N-acylated N-heteroarenes
por: Morioka, Toshifumi, et al.
Publicado: (2019)

A C-to-O atom-swapping reaction sequence enabled by Ni-catalyzed decarbonylation of lactones
por: Luu, Quang H., et al.
Publicado: (2022)

Unified synthesis of multiply arylated alkanes by catalytic deoxygenative transformation of diarylketones
por: Kurosawa, Miki B., et al.
Publicado: (2022)

A facile method for Rh-catalyzed decarbonylative ortho-C–H alkylation of (hetero)arenes with alkyl carboxylic acids
por: Tian, Yiqiang, et al.
Publicado: (2021)

Cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds
por: Barsu, Nagaraju, et al.
Publicado: (2017)

Cobalt nanoparticles-catalyzed aerobic oxygenation and esterification of alkynes via C≡C bonds cleavage
por: Li, Yujing, et al.
Publicado: (2023)

Cobalt-catalyzed, directed arylation of C–H bonds in N-aryl pyrazoles
por: Nguyen, Tung T., et al.
Publicado: (2021)

Correction: Cobalt-catalyzed, directed arylation of C–H bonds in N-aryl pyrazoles
por: Nguyen, Tung T., et al.
Publicado: (2021)

Photoinduced transition-metal- and external-photosensitizer-free intramolecular aryl rearrangement via C(Ar)–O bond cleavage
por: Dou, Qian, et al.
Publicado: (2020)

Light-driven transition-metal-free direct decarbonylation of unstrained diaryl ketones via a dual C–C bond cleavage
por: Cao, Dawei, et al.
Publicado: (2022)

Rh-catalyzed decarbonylation of conjugated ynones via carbon–alkyne bond activation: reaction scope and mechanistic exploration via DFT calculations
por: Dermenci, Alpay, et al.
Publicado: (2015)

Cobalt-catalyzed multisubstituted allylation of the chelation-assisted C–H bond of (hetero)arenes with cyclopropenes
por: Ramachandran, Kuppan, et al.
Publicado: (2021)

Copper-catalyzed enantioselective diyne cyclization via C(sp(2))–O bond cleavage
por: Zhou, Ji-Jia, et al.
Publicado: (2023)

How intramolecular coordination bonding (ICB) controls the homolysis of the C–ON bond in alkoxyamines
por: Audran, Gérard, et al.
Publicado: (2019)

Efficient C–H bond activations via O(2) cleavage by a dianionic cobalt(ii) complex
por: Nguyen, Andy I., et al.
Publicado: (2014)

Copper-catalyzed diastereoselective aerobic intramolecular dehydrogenative coupling of hydrazones via sp(3) C–H functionalization
por: Wu, Xuesong, et al.
Publicado: (2015)

Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity
por: Khosrowabadi Kotyk, Juliet F., et al.
Publicado: (2018)

Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage
por: Liu, Huijin, et al.
Publicado: (2022)

Rhodium(i)-catalyzed stereoselective [4+2] cycloaddition of oxetanols with alkynes through C(sp(3))–C(sp(3)) bond cleavage
por: Guo, Rui, et al.
Publicado: (2017)

Palladium‐Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides
por: Keaveney, Sinead T., et al.
Publicado: (2018)

Palladium/Norbornene-Catalyzed Decarbonylative Difunctionalization of Thioesters
por: Han, Ming-Liang, et al.
Publicado: (2021)

Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp(3))–heteroatom bonds
por: Ge, Liang, et al.
Publicado: (2022)

Iodine-catalyzed synthesis of benzoxazoles using catechols, ammonium acetate, and alkenes/alkynes/ketones via C–C and C–O bond cleavage
por: Aboonajmi, Jasem, et al.
Publicado: (2022)

Cobalt-Catalyzed, Aminoquinoline-Directed Coupling of sp(2) C–H Bonds with Alkenes
por: Grigorjeva, Liene, et al.
Publicado: (2014)

Nickel catalyzed intramolecular oxidative coupling: synthesis of 3-aryl benzofurans
por: Aggarwal, Sakshi, et al.
Publicado: (2020)

Cobalt-catalyzed C(sp(3))–H/C(sp(2))–H oxidative coupling between alkanes and benzamides
por: Li, Shuangjie, et al.
Publicado: (2018)

Oxidative C−C bond cleavage of lignin via electrocatalysis
por: Huang, Jinshu, et al.
Publicado: (2022)

Copper catalyzed borocarbonylation of benzylidenecyclopropanes through selective proximal C–C bond cleavage: synthesis of γ-boryl-γ,δ-unsaturated carbonyl compounds
por: Yang, Li-Miao, et al.
Publicado: (2022)

Novel synthesis of divergent aryl imidazoles from ketones involving copper-catalyzed α-amination and oxidative C–C bond cleavage
por: Huang, Jiangkun, et al.
Publicado: (2020)

Transition metal-free intramolecular regioselective couplings of aliphatic and aromatic C-H bonds
por: Tian, Hua, et al.
Publicado: (2016)

Iron-catalyzed tandem reaction of C–Se bond coupling/selenosulfonation of indols with benzeneselenols
por: Guan, Senling, et al.
Publicado: (2020)

Transition-metal free C–C bond cleavage/borylation of cycloketone oxime esters
por: Zhang, Jin-Jiang, et al.
Publicado: (2018)

Decarbonylative ether dissection by iridium pincer complexes
por: Yoo, Changho, et al.
Publicado: (2020)

Gold-Catalyzed Synthesis of Tetrazoles from Alkynes by C=C Bond Cleavage**
por: Gaydou, Morgane, et al.
Publicado: (2013)

Synthesis of Biaryls via Decarbonylative Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Carboxylic Acids
por: Liu, Chengwei, et al.
Publicado: (2019)

Synthesis of 5,6-Dihydrophenanthridines via Palladium-Catalyzed Intramolecular Dehydrogenative Coupling of Two Aryl C−H Bonds
por: Wang, Meng-Yue, et al.
Publicado: (2023)

Palladium-catalyzed intramolecular enantioselective C(sp(3))–H insertion of donor/donor carbenes
por: Li, Wendeng, et al.
Publicado: (2022)

Cu-catalyzed oxygenation of alkene-tethered amides with O(2)via unactivated C[double bond, length as m-dash]C bond cleavage: a direct approach to cyclic imides
por: Li, Junhua, et al.
Publicado: (2019)

Rhodium(i)-catalyzed asymmetric [4 + 2] cycloaddition reactions of 2-alkylenecyclobutanols with cyclic enones through C–C bond cleavage: efficient access to trans-bicyclic compounds
por: Zheng, Xinxin, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_hf7itrm4lf2s1najlocq2a5fge