Cargando…

Synthetic half-reactions

This perspective on reactivity introduces Synthetic Half-Reactions (SHRs) as a way to analyze chemical transformations. SHRs denote either an uphill transformation leading to a higher energy state or a downhill transformation leading to a lower energy state. Using well-established processes, I show...

Descripción completa

Detalles Bibliográficos
Autor principal: Yudin, Andrei K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162983/
https://www.ncbi.nlm.nih.gov/pubmed/34094448
http://dx.doi.org/10.1039/d0sc03876h
_version_ 1783700816707715072
author Yudin, Andrei K.
author_facet Yudin, Andrei K.
author_sort Yudin, Andrei K.
collection PubMed
description This perspective on reactivity introduces Synthetic Half-Reactions (SHRs) as a way to analyze chemical transformations. SHRs denote either an uphill transformation leading to a higher energy state or a downhill transformation leading to a lower energy state. Using well-established processes, I show how the matching of different classes of SHRs offers a tool to classify chemical transformations. This raises the possibility to discover new processes by finding underappreciated combinations of endergonic and exergonic steps.
format Online
Article
Text
id pubmed-8162983
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-81629832021-06-04 Synthetic half-reactions Yudin, Andrei K. Chem Sci Chemistry This perspective on reactivity introduces Synthetic Half-Reactions (SHRs) as a way to analyze chemical transformations. SHRs denote either an uphill transformation leading to a higher energy state or a downhill transformation leading to a lower energy state. Using well-established processes, I show how the matching of different classes of SHRs offers a tool to classify chemical transformations. This raises the possibility to discover new processes by finding underappreciated combinations of endergonic and exergonic steps. The Royal Society of Chemistry 2020-09-09 /pmc/articles/PMC8162983/ /pubmed/34094448 http://dx.doi.org/10.1039/d0sc03876h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Yudin, Andrei K.
Synthetic half-reactions
title Synthetic half-reactions
title_full Synthetic half-reactions
title_fullStr Synthetic half-reactions
title_full_unstemmed Synthetic half-reactions
title_short Synthetic half-reactions
title_sort synthetic half-reactions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162983/
https://www.ncbi.nlm.nih.gov/pubmed/34094448
http://dx.doi.org/10.1039/d0sc03876h
work_keys_str_mv AT yudinandreik synthetichalfreactions