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Nature of the copper-nitrosyl intermediates of copper nitrite reductases during catalysis

The design and synthesis of copper complexes that can reduce nitrite to NO has attracted considerable interest. They have been guided by the structural information on the catalytic Cu centre of the widespread enzymes Cu nitrite reductases but the chemically novel side-on binding of NO observed in al...

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Detalles Bibliográficos
Autores principales: Hough, Michael A., Conradie, Jeanet, Strange, Richard W., Antonyuk, Svetlana V., Eady, Robert R., Ghosh, Abhik, Hasnain, S. Samar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163067/
https://www.ncbi.nlm.nih.gov/pubmed/34094452
http://dx.doi.org/10.1039/d0sc04797j