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Driving high quantum yield NIR emission through proquinoidal linkage motifs in conjugated supermolecular arrays

High quantum yield NIR fluorophores are rare. Factors that drive low emission quantum yields at long wavelength include the facts that radiative rate constants increase proportional to the cube of the emission energy, while nonradiative rate constants increase in an approximately exponentially with...

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Detalles Bibliográficos
Autores principales: Peterson, Erin J., Qi, Wei, Stanton, Ian N., Zhang, Peng, Therien, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163388/
https://www.ncbi.nlm.nih.gov/pubmed/34123083
http://dx.doi.org/10.1039/d0sc03446k