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Palladium catalyzed carbonylative generation of potent, pyridine-based acylating electrophiles for the functionalization of arenes to ketones

We describe here the design of a palladium catalyzed route to generate aryl ketones via the carbonylative coupling of (hetero)arenes and aryl- or vinyl-triflates. In this, the use of the large bite angle Xantphos ligand on palladium provides a unique avenue to balance the activation of the relativel...

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Detalles Bibliográficos
Autores principales:	Liu, Yi, Kaiser, Angela M., Arndtsen, Bruce A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163404/ https://www.ncbi.nlm.nih.gov/pubmed/34123121 http://dx.doi.org/10.1039/d0sc03129a

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