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Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks
In this perspective, we feature recent advances in the field of actinide-containing metal–organic frameworks (An-MOFs) with a main focus on their electronic, catalytic, photophysical, and sorption properties. This discussion deviates from a strictly crystallographic analysis of An-MOFs, reported in...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8171348/ https://www.ncbi.nlm.nih.gov/pubmed/34163816 http://dx.doi.org/10.1039/d1sc01827b |
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author | Martin, Corey R. Leith, Gabrielle A. Shustova, Natalia B. |
author_facet | Martin, Corey R. Leith, Gabrielle A. Shustova, Natalia B. |
author_sort | Martin, Corey R. |
collection | PubMed |
description | In this perspective, we feature recent advances in the field of actinide-containing metal–organic frameworks (An-MOFs) with a main focus on their electronic, catalytic, photophysical, and sorption properties. This discussion deviates from a strictly crystallographic analysis of An-MOFs, reported in several reviews, or synthesis of novel structural motifs, and instead delves into the remarkable potential of An-MOFs for evolving the nuclear waste administration sector. Currently, the An-MOF field is dominated by thorium- and uranium-containing structures, with only a few reports on transuranic frameworks. However, some of the reported properties in the field of An-MOFs foreshadow potential implementation of these materials and are the main focus of this report. Thus, this perspective intends to provide a glimpse into the challenges, triumphs, and future directions of An-MOFs in sectors ranging from the traditional realm of gas sorption and separation to recently emerging areas such as electronics and photophysics. |
format | Online Article Text |
id | pubmed-8171348 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-81713482021-06-22 Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks Martin, Corey R. Leith, Gabrielle A. Shustova, Natalia B. Chem Sci Chemistry In this perspective, we feature recent advances in the field of actinide-containing metal–organic frameworks (An-MOFs) with a main focus on their electronic, catalytic, photophysical, and sorption properties. This discussion deviates from a strictly crystallographic analysis of An-MOFs, reported in several reviews, or synthesis of novel structural motifs, and instead delves into the remarkable potential of An-MOFs for evolving the nuclear waste administration sector. Currently, the An-MOF field is dominated by thorium- and uranium-containing structures, with only a few reports on transuranic frameworks. However, some of the reported properties in the field of An-MOFs foreshadow potential implementation of these materials and are the main focus of this report. Thus, this perspective intends to provide a glimpse into the challenges, triumphs, and future directions of An-MOFs in sectors ranging from the traditional realm of gas sorption and separation to recently emerging areas such as electronics and photophysics. The Royal Society of Chemistry 2021-05-13 /pmc/articles/PMC8171348/ /pubmed/34163816 http://dx.doi.org/10.1039/d1sc01827b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Martin, Corey R. Leith, Gabrielle A. Shustova, Natalia B. Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks |
title | Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks |
title_full | Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks |
title_fullStr | Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks |
title_full_unstemmed | Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks |
title_short | Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks |
title_sort | beyond structural motifs: the frontier of actinide-containing metal–organic frameworks |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8171348/ https://www.ncbi.nlm.nih.gov/pubmed/34163816 http://dx.doi.org/10.1039/d1sc01827b |
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