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U(2)N@I(h)(7)-C(80): fullerene cage encapsulating an unsymmetrical U(iv)[double bond, length as m-dash]N[double bond, length as m-dash]U(v) cluster
For the first time, an actinide nitride clusterfullerene, U(2)N@I(h)(7)-C(80), is synthesized and fully characterized by X-ray single crystallography and multiple spectroscopic methods. U(2)N@I(h)(7)-C(80) is by far the first endohedral fullerene that violates the well-established tri-metallic nitri...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8178745/ https://www.ncbi.nlm.nih.gov/pubmed/34163596 http://dx.doi.org/10.1039/d0sc04677a |