Delocalization tunable by ligand substitution in [L(2)Al](n−) complexes highlights a mechanism for strong electronic coupling

Ligand-based mixed valent (MV) complexes of Al(iii) incorporating electron donating (ED) and electron withdrawing (EW) substituents on bis(imino)pyridine ligands (I(2)P) have been prepared. The MV states containing EW groups are both assigned as Class II/III, and those with ED functional groups are...

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Detalles Bibliográficos
Autores principales: Arnold, Amela, Sherbow, Tobias J., Bohanon, Amanda M., Sayler, Richard I., Britt, R. David, Smith, Allison M., Fettinger, James C., Berben, Louise A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179017/
https://www.ncbi.nlm.nih.gov/pubmed/34163799
http://dx.doi.org/10.1039/d0sc02812f

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