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Visible-light-driven palladium-catalyzed Dowd–Beckwith ring expansion/C–C bond formation cascade

A visible-light-induced palladium-catalyzed Dowd–Beckwith ring expansion/C–C bond formation cascade is described. A range of six to nine-membered β-alkenylated cyclic ketones possessing a quaternary carbon center were accessed under mild conditions. Besides styrenes, the electron-rich alkenes such a...

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Detalles Bibliográficos
Autores principales: Chen, Li, Guo, Li-Na, Liu, Shuai, Liu, Le, Duan, Xin-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179048/
https://www.ncbi.nlm.nih.gov/pubmed/34163941
http://dx.doi.org/10.1039/d0sc04399k

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