Interplay between spin crossover and proton migration along short strong hydrogen bonds

The iron(ii) salt [Fe(bpp)(2)](isonicNO)(2)·HisonicNO·5H(2)O (1) (bpp = 2,6-bis(pyrazol-3-yl)pyridine; isonicNO = isonicotinate N-oxide anion) undergoes a partial spin crossover (SCO) with symmetry breaking at T(1) = 167 K to a mixed-spin phase (50% high-spin (HS), 50% low-spin (LS)) that is metasta...

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Detalles Bibliográficos
Autores principales: Jornet-Mollá, Verónica, Giménez-Saiz, Carlos, Cañadillas-Delgado, Laura, Yufit, Dmitry S., Howard, Judith A. K., Romero, Francisco M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179063/
https://www.ncbi.nlm.nih.gov/pubmed/34163870
http://dx.doi.org/10.1039/d0sc04918b

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