Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate

We report the use of electron rich iron complexes supported by a dianionic diborate pentadentate ligand system, B(2)Pz(4)Py, for the coordination and activation of ammonia (NH(3)) and hydrazine (NH(2)NH(2)). For ammonia, coordination to neutral (B(2)Pz(4)Py)Fe(ii) or cationic [(B(2)Pz(4)Py)Fe(iii)](...

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Detalles Bibliográficos
Autores principales: Nurdin, Lucie, Yang, Yan, Neate, Peter G. N., Piers, Warren E., Maron, Laurent, Neidig, Michael L., Lin, Jian-Bin, Gelfand, Benjamin S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179247/
https://www.ncbi.nlm.nih.gov/pubmed/34163989
http://dx.doi.org/10.1039/d0sc06466a

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