Iridium-promoted deoxyglycoside synthesis: stereoselectivity and mechanistic insight

Herein, we devised a method for stereoselective O-glycosylation using an Ir(i)-catalyst which enables both hydroalkoxylation and nucleophilic substitution of glycals with varying substituents at the C3 position. In this transformation, 2-deoxy-α-O-glycosides were acquired when glycals equipped with...

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Detalles Bibliográficos
Autores principales: Pal, Kumar Bhaskar, Guo, Aoxin, Das, Mrinmoy, Lee, Jiande, Báti, Gábor, Yip, Benjamin Rui Peng, Loh, Teck-Peng, Liu, Xue-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179265/
https://www.ncbi.nlm.nih.gov/pubmed/34163986
http://dx.doi.org/10.1039/d0sc06529c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179265/
https://www.ncbi.nlm.nih.gov/pubmed/34163986
http://dx.doi.org/10.1039/d0sc06529c

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