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Magnesium–halobenzene bonding: mapping the halogen sigma-hole with a Lewis-acidic complex

Complexes of the Lewis base-free cations ((Me)BDI)Mg(+) and ((tBu)BDI)Mg(+) with Ph–X ligands (X = F, Cl, Br, I) have been studied ((Me)BDI = HC[C(Me)N-DIPP](2) and (tBu)BDI = HC[C(tBu)N-DIPP](2); DIPP = 2,6-diisopropylphenyl). For the smaller β-diketiminate ligand ((Me)BDI) only complexes with PhF...

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Detalles Bibliográficos
Autores principales:	Friedrich, Alexander, Pahl, Jürgen, Eyselein, Jonathan, Langer, Jens, van Eikema Hommes, Nico, Görling, Andreas, Harder, Sjoerd
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179342/ https://www.ncbi.nlm.nih.gov/pubmed/34164006 http://dx.doi.org/10.1039/d0sc06321e

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