Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens

We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such solids into physical mixtures of their constituents. Computational me...

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Autores principales: Arhangelskis, Mihails, Bučar, Dejan-Krešimir, Bordignon, Simone, Chierotti, Michele R., Stratford, Samuel A., Voinovich, Dario, Jones, William, Hasa, Dritan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179350/
https://www.ncbi.nlm.nih.gov/pubmed/34164095
http://dx.doi.org/10.1039/d0sc05071g
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author Arhangelskis, Mihails
Bučar, Dejan-Krešimir
Bordignon, Simone
Chierotti, Michele R.
Stratford, Samuel A.
Voinovich, Dario
Jones, William
Hasa, Dritan
author_facet Arhangelskis, Mihails
Bučar, Dejan-Krešimir
Bordignon, Simone
Chierotti, Michele R.
Stratford, Samuel A.
Voinovich, Dario
Jones, William
Hasa, Dritan
author_sort Arhangelskis, Mihails
collection PubMed
description We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such solids into physical mixtures of their constituents. Computational methods were employed in an attempt to identify possible reasons for these previously unrecognised effects of liquid additives on mechanochemical transformations.
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spelling pubmed-81793502021-06-22 Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens Arhangelskis, Mihails Bučar, Dejan-Krešimir Bordignon, Simone Chierotti, Michele R. Stratford, Samuel A. Voinovich, Dario Jones, William Hasa, Dritan Chem Sci Chemistry We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such solids into physical mixtures of their constituents. Computational methods were employed in an attempt to identify possible reasons for these previously unrecognised effects of liquid additives on mechanochemical transformations. The Royal Society of Chemistry 2021-01-20 /pmc/articles/PMC8179350/ /pubmed/34164095 http://dx.doi.org/10.1039/d0sc05071g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Arhangelskis, Mihails
Bučar, Dejan-Krešimir
Bordignon, Simone
Chierotti, Michele R.
Stratford, Samuel A.
Voinovich, Dario
Jones, William
Hasa, Dritan
Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens
title Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens
title_full Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens
title_fullStr Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens
title_full_unstemmed Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens
title_short Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens
title_sort mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179350/
https://www.ncbi.nlm.nih.gov/pubmed/34164095
http://dx.doi.org/10.1039/d0sc05071g
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