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Catalytic enantioselective synthesis of macrodiolides and their application in chiral recognition

New types of C(2)-symmetric chiral macrodiolides are readily obtained via chiral N,N′-dioxide-scandium(iii) complex-promoted asymmetric tandem Friedel–Crafts alkylation/intermolecular macrolactonization of ortho-quinone methides with C3-substituted indoles. This protocol provides an array of enantio...

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Detalles Bibliográficos
Autores principales:	Xiao, Wanlong, Mo, Yuhao, Guo, Jing, Su, Zhishan, Dong, Shunxi, Feng, Xiaoming
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179366/ https://www.ncbi.nlm.nih.gov/pubmed/34164061 http://dx.doi.org/10.1039/d0sc06162j

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