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Reversible Pt(II)–CH(3) deuteration without methane loss: metal–ligand cooperation vs. ligand-assisted Pt(II)-protonation
Di(2-pyridyl)ketone dimethylplatinum(ii), (dpk)Pt(II)(CH(3))(2), reacts with CD(3)OD at 25 °C to undergo complete deuteration of Pt–CH(3) fragments in ∼5 h without loss of methane to form (dpk)Pt(II)(CD(3))(2) in virtually quantitative yield. The deuteration can be reversed by dissolution in CH(3)OH...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179389/ https://www.ncbi.nlm.nih.gov/pubmed/34164064 http://dx.doi.org/10.1039/d0sc06518h |