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Polyolefin catalysis of propene, 1-butene and isobutene monitored using hyperpolarized NMR
Polymerization reactions of the dissolved gases propene, 1-butene, and isobutene catalyzed by [Zr(Cp)(2)Me][B(C(6)F(5))(4)] were characterized using in situ NMR. Hyperpolarization of (13)C spins by the dissolution dynamic nuclear polarization (DNP) technique provided a signal enhancement of up to 50...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179394/ https://www.ncbi.nlm.nih.gov/pubmed/34164046 http://dx.doi.org/10.1039/d0sc05408a |