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Dehydrogenation of iron amido-borane and resaturation of the imino-borane complex
We report on the first isolation and structural characterization of an iron phosphinoimino-borane complex Cp*Fe(η(2)-H(2)B[double bond, length as m-dash]NC(6)H(4)PPh(2)) by dehydrogenation of iron amido-borane precursor Cp*Fe(η(1)-H(3)B–NHC(6)H(4)PPh(2)). Significantly, regeneration of the amido-bor...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179412/ https://www.ncbi.nlm.nih.gov/pubmed/34164054 http://dx.doi.org/10.1039/d0sc06787c |