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Benzylic C(sp(3))–C(sp(2)) cross-coupling of indoles enabled by oxidative radical generation and nickel catalysis
A mechanistically unique functionalization strategy for a benzylic C(sp(3))–H bond has been developed based on the facile oxidation event of indole substrates. This novel pathway was initiated by efficient radical generation at the benzylic position of the substrate, with subsequent transition metal...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179435/ https://www.ncbi.nlm.nih.gov/pubmed/34163683 http://dx.doi.org/10.1039/d0sc06666d |