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Ruthenium-catalyzed formal sp(3) C–H activation of allylsilanes/esters with olefins: efficient access to functionalized 1,3-dienes
Ru-catalysed oxidative coupling of allylsilanes and allyl esters with activated olefins has been developed via isomerization followed by C(allyl)–H activation providing efficient access to stereodefined 1,3-dienes in excellent yields. Mild reaction conditions, less expensive catalysts, and excellent...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179449/ https://www.ncbi.nlm.nih.gov/pubmed/34163699 http://dx.doi.org/10.1039/d0sc06845d |