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Ruthenium-catalyzed formal sp(3) C–H activation of allylsilanes/esters with olefins: efficient access to functionalized 1,3-dienes

Ru-catalysed oxidative coupling of allylsilanes and allyl esters with activated olefins has been developed via isomerization followed by C(allyl)–H activation providing efficient access to stereodefined 1,3-dienes in excellent yields. Mild reaction conditions, less expensive catalysts, and excellent...

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Detalles Bibliográficos
Autores principales:	Dethe, Dattatraya H., Beeralingappa, Nagabhushana C., Das, Saikat, Nirpal, Appasaheb K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179449/ https://www.ncbi.nlm.nih.gov/pubmed/34163699 http://dx.doi.org/10.1039/d0sc06845d

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