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Ligand-enforced intimacy between a gold cation and a carbenium ion: impact on stability and reactivity
Controlling the reactivity of transition metal complexes by positioning non-innocent functionalities around the catalytic pocket is a concept that has led to significant advances in catalysis. Here we describe our efforts toward the synthesis of dicationic phosphine gold complexes of general formula...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179465/ https://www.ncbi.nlm.nih.gov/pubmed/34163662 http://dx.doi.org/10.1039/d0sc05777k |