Cerium(iv) complexes with guanidinate ligands: intense colors and anomalous electronic structures

A series of cerium(iv) mixed-ligand guanidinate–amide complexes, {[(Me(3)Si)(2)NC(N(i)Pr)(2)](x)Ce(IV)[N(SiMe(3))(2)](3−x)}(+) (x = 0–3), was prepared by chemical oxidation of the corresponding cerium(iii) complexes, where x = 1 and 2 represent novel complexes. The Ce(iv) complexes exhibited a range...

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Detalles Bibliográficos
Autores principales: Qiao, Yusen, Yin, Haolin, Moreau, Liane M., Feng, Rulin, Higgins, Robert F., Manor, Brian C., Carroll, Patrick J., Booth, Corwin H., Autschbach, Jochen, Schelter, Eric J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179493/
https://www.ncbi.nlm.nih.gov/pubmed/34163629
http://dx.doi.org/10.1039/d0sc05193d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179493/
https://www.ncbi.nlm.nih.gov/pubmed/34163629
http://dx.doi.org/10.1039/d0sc05193d

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