Cargando…
Selective cleavage of unactivated arene ring C–C bonds by iridium: key roles of benzylic C–H activation and metal–metal cooperativity
The cleavage of aromatic C–C bonds is central for conversion of fossil fuels into industrial chemicals and designing novel arene functionalisations through ring opening, expansion and contraction. However, the current progress is hampered by both the lack of experimental examples of selective oxidat...
Autores principales: | Tian, Yancong, Jakoobi, Martin, Boulatov, Roman, Sergeev, Alexey G. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179494/ https://www.ncbi.nlm.nih.gov/pubmed/34163630 http://dx.doi.org/10.1039/d0sc05900e |
Ejemplares similares
-
Selective ortho-C–H Activation
in Arenes without Functional Groups
por: Chan, Antony P. Y., et al.
Publicado: (2022) -
Formal C−H Carboxylation of Unactivated Arenes
por: Gevorgyan, Ashot, et al.
Publicado: (2020) -
Small organic molecules with tailored structures: initiators in the transition-metal-free C–H arylation of unactivated arenes
por: Liu, Zhenghui, et al.
Publicado: (2020) -
Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp(3))–H bonds
por: Wu, Xinxin, et al.
Publicado: (2018) -
Transition-metal free C–C bond cleavage/borylation of cycloketone oxime esters
por: Zhang, Jin-Jiang, et al.
Publicado: (2018)