Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes

Chiral, cationic NHC–iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes. The catalysts show high activity in the construction of a range of 5- and 6-membered N-heterocycles, which are accessed in excellent optical purity, with var...

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Detalles Bibliográficos
Autores principales: Foster, Daven, Gao, Pengchao, Zhang, Ziyun, Sipos, Gellért, Sobolev, Alexandre N., Nealon, Gareth, Falivene, Laura, Cavallo, Luigi, Dorta, Reto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179506/
https://www.ncbi.nlm.nih.gov/pubmed/34163649
http://dx.doi.org/10.1039/d0sc05884j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179506/
https://www.ncbi.nlm.nih.gov/pubmed/34163649
http://dx.doi.org/10.1039/d0sc05884j

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