Using internal electrostatic fields to manipulate the valence manifolds of copper complexes

A series of tetradentate tris(phosphinimine) ligands ((R3)P(3)tren) was developed and bound to Cu(I) to form the trigonal pyramidal, C(3v)-symmetric cuprous complexes [(R3)P(3)tren-Cu][BAr(F)(4)] (1PR3) (PR(3) = PMe(3), PMe(2)Ph, PMePh(2), PPh(3), PMe(2)(NEt(2)), BAr(F)(4) = B(C(6)F(5))(4)). Electro...

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Detalles Bibliográficos
Autores principales: Weberg, Alexander B., McCollom, Samuel P., Thierer, Laura M., Gau, Michael R., Carroll, Patrick J., Tomson, Neil C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179517/
https://www.ncbi.nlm.nih.gov/pubmed/34163703
http://dx.doi.org/10.1039/d0sc06364a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179517/
https://www.ncbi.nlm.nih.gov/pubmed/34163703
http://dx.doi.org/10.1039/d0sc06364a

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