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Using internal electrostatic fields to manipulate the valence manifolds of copper complexes
A series of tetradentate tris(phosphinimine) ligands ((R3)P(3)tren) was developed and bound to Cu(I) to form the trigonal pyramidal, C(3v)-symmetric cuprous complexes [(R3)P(3)tren-Cu][BAr(F)(4)] (1PR3) (PR(3) = PMe(3), PMe(2)Ph, PMePh(2), PPh(3), PMe(2)(NEt(2)), BAr(F)(4) = B(C(6)F(5))(4)). Electro...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179517/ https://www.ncbi.nlm.nih.gov/pubmed/34163703 http://dx.doi.org/10.1039/d0sc06364a |