Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”

The reaction between basic [(PCP)Pd(H)] (PCP = 2,6-(CH(2)P(t-C(4)H(9))(2))(2)C(6)H(4)) and acidic [LWH(CO)(3)] (L = Cp (1a), Tp (1b); Cp = η(5)-cyclopentadienyl, Tp = κ(3)-hydridotris(pyrazolyl)borate) leads to the formation of bimolecular complexes [LW(CO)(2)(μ-CO)⋯Pd(PCP)] (4a, 4b), which catalyze...

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Detalles Bibliográficos
Autores principales: Osipova, Elena S., Gulyaeva, Ekaterina S., Gutsul, Evgenii I., Kirkina, Vladislava A., Pavlov, Alexander A., Nelyubina, Yulia V., Rossin, Andrea, Peruzzini, Maurizio, Epstein, Lina M., Belkova, Natalia V., Filippov, Oleg A., Shubina, Elena S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179527/
https://www.ncbi.nlm.nih.gov/pubmed/34163642
http://dx.doi.org/10.1039/d0sc06114j

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