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Acyl metalloids: conformity and deviation from carbonyl reactivity
Once considered as mere curiosities, acyl metalloids are now recognized for their utility in enabling chemical synthesis. This perspective considers the reactivity displayed by acylboron, -silicon, -germanium, and tellurium species. By highlighting the role of these species in various transformation...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179550/ https://www.ncbi.nlm.nih.gov/pubmed/34163766 http://dx.doi.org/10.1039/d1sc00077b |
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author | Holownia, Aleksandra Apte, Chirag N. Yudin, Andrei K. |
author_facet | Holownia, Aleksandra Apte, Chirag N. Yudin, Andrei K. |
author_sort | Holownia, Aleksandra |
collection | PubMed |
description | Once considered as mere curiosities, acyl metalloids are now recognized for their utility in enabling chemical synthesis. This perspective considers the reactivity displayed by acylboron, -silicon, -germanium, and tellurium species. By highlighting the role of these species in various transformations, we demonstrate how differences between the comprising elements result in varied reaction outcomes. While acylboron compounds are primarily used in polar transformations, germanium and tellurium species have found utility as radical precursors. Applications of acylsilanes are comparatively more diverse, owing to the possibility to access both radical and polar chemistry. |
format | Online Article Text |
id | pubmed-8179550 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-81795502021-06-22 Acyl metalloids: conformity and deviation from carbonyl reactivity Holownia, Aleksandra Apte, Chirag N. Yudin, Andrei K. Chem Sci Chemistry Once considered as mere curiosities, acyl metalloids are now recognized for their utility in enabling chemical synthesis. This perspective considers the reactivity displayed by acylboron, -silicon, -germanium, and tellurium species. By highlighting the role of these species in various transformations, we demonstrate how differences between the comprising elements result in varied reaction outcomes. While acylboron compounds are primarily used in polar transformations, germanium and tellurium species have found utility as radical precursors. Applications of acylsilanes are comparatively more diverse, owing to the possibility to access both radical and polar chemistry. The Royal Society of Chemistry 2021-03-10 /pmc/articles/PMC8179550/ /pubmed/34163766 http://dx.doi.org/10.1039/d1sc00077b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Holownia, Aleksandra Apte, Chirag N. Yudin, Andrei K. Acyl metalloids: conformity and deviation from carbonyl reactivity |
title | Acyl metalloids: conformity and deviation from carbonyl reactivity |
title_full | Acyl metalloids: conformity and deviation from carbonyl reactivity |
title_fullStr | Acyl metalloids: conformity and deviation from carbonyl reactivity |
title_full_unstemmed | Acyl metalloids: conformity and deviation from carbonyl reactivity |
title_short | Acyl metalloids: conformity and deviation from carbonyl reactivity |
title_sort | acyl metalloids: conformity and deviation from carbonyl reactivity |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179550/ https://www.ncbi.nlm.nih.gov/pubmed/34163766 http://dx.doi.org/10.1039/d1sc00077b |
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