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An unexpected P-cluster like intermediate en route to the nitrogenase FeMo-co

The nitrogenase MoFe protein contains two different FeS centers, the P-cluster and the iron–molybdenum cofactor (FeMo-co). The former is a [Fe(8)S(7)] center responsible for conveying electrons to the latter, a [MoFe(7)S(9)C-(R)-homocitrate] species, where N(2) reduction takes place. NifB is arguabl...

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Detalles Bibliográficos
Autores principales:	Jenner, Leon P., Cherrier, Mickael V., Amara, Patricia, Rubio, Luis M., Nicolet, Yvain
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179604/ https://www.ncbi.nlm.nih.gov/pubmed/34168778 http://dx.doi.org/10.1039/d1sc00289a

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