Anion-enhanced excited state charge separation in a spiro-locked N-heterocycle-fused push-pull zinc porphyrin

A new type of push–pull charge transfer complex, viz., a spiro-locked N-heterocycle-fused zinc porphyrin, ZnP-SQ, is shown to undergo excited state charge separation, which is enhanced by axial F(−) binding to the Zn center. In this push–pull design, the spiro-quinone group acts as a ‘lock’ promotin...

Descripción completa

Detalles Bibliográficos
Autores principales: Chahal, Mandeep K., Liyanage, Anuradha, Alsaleh, Ajyal Z., Karr, Paul A., Hill, Jonathan P., D'Souza, Francis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179616/
https://www.ncbi.nlm.nih.gov/pubmed/34168764
http://dx.doi.org/10.1039/d1sc00038a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179616/
https://www.ncbi.nlm.nih.gov/pubmed/34168764
http://dx.doi.org/10.1039/d1sc00038a

Ejemplares similares