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Trioxatriangulenium (TOTA(+)) as a robust carbon-based Lewis acid in frustrated Lewis pair chemistry
We report the reactivity between the water stable Lewis acidic trioxatriangulenium ion (TOTA(+)) and a series of Lewis bases such as phosphines and N-heterocyclic carbene (NHC). The nature of the Lewis acid–base interaction was analyzed via variable temperature (VT) NMR spectroscopy, single-crystal...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179643/ https://www.ncbi.nlm.nih.gov/pubmed/34168760 http://dx.doi.org/10.1039/d0sc05893a |