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Trioxatriangulenium (TOTA(+)) as a robust carbon-based Lewis acid in frustrated Lewis pair chemistry

We report the reactivity between the water stable Lewis acidic trioxatriangulenium ion (TOTA(+)) and a series of Lewis bases such as phosphines and N-heterocyclic carbene (NHC). The nature of the Lewis acid–base interaction was analyzed via variable temperature (VT) NMR spectroscopy, single-crystal...

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Detalles Bibliográficos
Autores principales:	Shaikh, Aslam C., Veleta, José M., Moutet, Jules, Gianetti, Thomas L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179643/ https://www.ncbi.nlm.nih.gov/pubmed/34168760 http://dx.doi.org/10.1039/d0sc05893a

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