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μ-Methyl­ene-bis­[di­bromido(diethyl ether-κO)aluminium(III)]: crystal structure and chemical exchange in solution

In the title compound, [Al(2)Br(4)(CH(2))(C(4)H(10)O)(2)], the mol­ecule lies on a crystallographic twofold axis passing through the bridging C atom. Each Al(III) atom is four-coordinate, being bonded to two bromide ions, bridging the CH(2) group as well as the oxygen atom of a diethyl ether ligand...

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Detalles Bibliográficos
Autores principales: Butcher, Ray J., Purdy, Andrew P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8183446/
https://www.ncbi.nlm.nih.gov/pubmed/34164145
http://dx.doi.org/10.1107/S2056989021005302