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Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide

The title compound [systematic name: 2-([1,1′-biphen­yl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C(20)H(23)NO(2) was synthesized and its photoreactive properties in the crystalline state and in aceto­nitrile solution were investigated. The compound crystallizes in the chiral space group P2(1)2(1...

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Detalles Bibliográficos
Autores principales: Miyamoto, Hisakazu, Takahashi, Hiroki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8183449/
https://www.ncbi.nlm.nih.gov/pubmed/34164146
http://dx.doi.org/10.1107/S2056989021005387
Descripción
Sumario:The title compound [systematic name: 2-([1,1′-biphen­yl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C(20)H(23)NO(2) was synthesized and its photoreactive properties in the crystalline state and in aceto­nitrile solution were investigated. The compound crystallizes in the chiral space group P2(1)2(1)2(1). The crystal does not react under UV light irradiation, perhaps due to the presence of the biphenyl group. However, the compound is photoreactive in aceto­nitrile solution to give racemic 3-(p-phenyl­phen­yl)-3-hy­droxy-N-isopropyl-4,4-di­methyl­azetidin-2-one.