Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide

The title compound [systematic name: 2-([1,1′-biphen­yl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C(20)H(23)NO(2) was synthesized and its photoreactive properties in the crystalline state and in aceto­nitrile solution were investigated. The compound crystallizes in the chiral space group P2(1)2(1...

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Detalles Bibliográficos
Autores principales: Miyamoto, Hisakazu, Takahashi, Hiroki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8183449/
https://www.ncbi.nlm.nih.gov/pubmed/34164146
http://dx.doi.org/10.1107/S2056989021005387
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author Miyamoto, Hisakazu
Takahashi, Hiroki
author_facet Miyamoto, Hisakazu
Takahashi, Hiroki
author_sort Miyamoto, Hisakazu
collection PubMed
description The title compound [systematic name: 2-([1,1′-biphen­yl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C(20)H(23)NO(2) was synthesized and its photoreactive properties in the crystalline state and in aceto­nitrile solution were investigated. The compound crystallizes in the chiral space group P2(1)2(1)2(1). The crystal does not react under UV light irradiation, perhaps due to the presence of the biphenyl group. However, the compound is photoreactive in aceto­nitrile solution to give racemic 3-(p-phenyl­phen­yl)-3-hy­droxy-N-isopropyl-4,4-di­methyl­azetidin-2-one.
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spelling pubmed-81834492021-06-22 Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide Miyamoto, Hisakazu Takahashi, Hiroki Acta Crystallogr E Crystallogr Commun Research Communications The title compound [systematic name: 2-([1,1′-biphen­yl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C(20)H(23)NO(2) was synthesized and its photoreactive properties in the crystalline state and in aceto­nitrile solution were investigated. The compound crystallizes in the chiral space group P2(1)2(1)2(1). The crystal does not react under UV light irradiation, perhaps due to the presence of the biphenyl group. However, the compound is photoreactive in aceto­nitrile solution to give racemic 3-(p-phenyl­phen­yl)-3-hy­droxy-N-isopropyl-4,4-di­methyl­azetidin-2-one. International Union of Crystallography 2021-05-28 /pmc/articles/PMC8183449/ /pubmed/34164146 http://dx.doi.org/10.1107/S2056989021005387 Text en © Miyamoto and Takahashi 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Miyamoto, Hisakazu
Takahashi, Hiroki
Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide
title Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide
title_full Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide
title_fullStr Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide
title_full_unstemmed Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide
title_short Crystal structure and photoreactive behaviour of N,N-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide
title_sort crystal structure and photoreactive behaviour of n,n-diisoprop­yl(p-phenyl­phen­yl)glyoxyl­amide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8183449/
https://www.ncbi.nlm.nih.gov/pubmed/34164146
http://dx.doi.org/10.1107/S2056989021005387
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AT takahashihiroki crystalstructureandphotoreactivebehaviourofnndiisopropylpphenylphenylglyoxylamide

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