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Solvent-dependent fac/mer-isomerization and self-assembly of triply helical complexes bearing a pivot part
Tris–chelate metal complexes of unsymmetrical bidentate ligands can form two geometric stereoisomers, facial (fac) and meridional (mer) isomers. Due to the small difference in their properties, the highly-selective synthesis of one of the isomers is challenging. We now designed a series of tripodal...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188510/ https://www.ncbi.nlm.nih.gov/pubmed/34168824 http://dx.doi.org/10.1039/d1sc01529j |