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Solvent-dependent fac/mer-isomerization and self-assembly of triply helical complexes bearing a pivot part

Tris–chelate metal complexes of unsymmetrical bidentate ligands can form two geometric stereoisomers, facial (fac) and meridional (mer) isomers. Due to the small difference in their properties, the highly-selective synthesis of one of the isomers is challenging. We now designed a series of tripodal...

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Detalles Bibliográficos
Autores principales: Morozumi, Takuma, Matsuoka, Ryota, Nakamura, Takashi, Nabeshima, Tatsuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188510/
https://www.ncbi.nlm.nih.gov/pubmed/34168824
http://dx.doi.org/10.1039/d1sc01529j

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