Cargando…

Remodeling of N-Heterocyclic Iminato Ligand Frameworks for the Facile Synthesis of Isoureas from Alcohols and Carbodiimides Promoted by Organoactinide (Th, U) Complexes

[Image: see text] A new class of actinide complexes [(L)An(N{SiMe(3)}(2))(3)] (An = Th or U) (Th1–Th3 and U1–U3) supported by highly nucleophilic seven-membered N-heterocyclic iminato ligands were synthesized and fully characterized by single-crystal X-ray diffraction. These complexes were successfu...

Descripción completa

Detalles Bibliográficos
Autores principales: Makarov, Konstantin, Saha, Sayantani, Ghatak, Tapas, Fridman, Natalia, Eisen, Moris S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8190913/
https://www.ncbi.nlm.nih.gov/pubmed/34124491
http://dx.doi.org/10.1021/acsomega.1c01836