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Segmented-Block Poly(ether amide)s Containing Flexible Polydisperse Polyethyleneoxide Sequences and Rigid Aromatic Amide Moieties
We describe the synthesis and characterization of three novel aromatic diamines containing oxyethylene sequences of different lengths. These diamines were polymerized using the low-temperature solution polycondensation method with isophthaloyl chloride (IPC), terepthaloyl chloride (TPC), [1,1’-biphe...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8197558/ https://www.ncbi.nlm.nih.gov/pubmed/34070343 http://dx.doi.org/10.3390/ma14112804 |
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author | Trigo-López, Miriam Reglero Ruiz, José A. Peredo, Patricia D. Mendía, Aranzazu Muñoz, Asunción García, Félix C. García, José M. |
author_facet | Trigo-López, Miriam Reglero Ruiz, José A. Peredo, Patricia D. Mendía, Aranzazu Muñoz, Asunción García, Félix C. García, José M. |
author_sort | Trigo-López, Miriam |
collection | PubMed |
description | We describe the synthesis and characterization of three novel aromatic diamines containing oxyethylene sequences of different lengths. These diamines were polymerized using the low-temperature solution polycondensation method with isophthaloyl chloride (IPC), terepthaloyl chloride (TPC), [1,1’-biphenyl]-4,4’-dicarbonyl dichloride (BDC), and 4,4′-oxybis(benzoyl chloride) (OBE), obtaining twelve poly(ether amide)s with short segments of polydisperse polyethyleneoxide (PEO) sequences in the polymer backbone. These polymers show reasonably high molecular mass materials (Mw > 12,000), and the relationship between their structure and properties has been carefully studied. Compared with conventional polyamides containing monodisperse PEO sequences, the polydispersity of the PEO segments within the structural units exerts a significant influence on the crystallinity, flexibility, solubility, and the thermal properties of the polymers. For instance, the all-para oriented polyamides (TPCP-A), with an average number of 8.2 ethylenoxide units per structural unit can be transformed conventionally (T(m) = 259 °C) in comparison with thermally untransformable polymer with 2 ethylenoxide units (T(m) = 425 °C). |
format | Online Article Text |
id | pubmed-8197558 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-81975582021-06-13 Segmented-Block Poly(ether amide)s Containing Flexible Polydisperse Polyethyleneoxide Sequences and Rigid Aromatic Amide Moieties Trigo-López, Miriam Reglero Ruiz, José A. Peredo, Patricia D. Mendía, Aranzazu Muñoz, Asunción García, Félix C. García, José M. Materials (Basel) Article We describe the synthesis and characterization of three novel aromatic diamines containing oxyethylene sequences of different lengths. These diamines were polymerized using the low-temperature solution polycondensation method with isophthaloyl chloride (IPC), terepthaloyl chloride (TPC), [1,1’-biphenyl]-4,4’-dicarbonyl dichloride (BDC), and 4,4′-oxybis(benzoyl chloride) (OBE), obtaining twelve poly(ether amide)s with short segments of polydisperse polyethyleneoxide (PEO) sequences in the polymer backbone. These polymers show reasonably high molecular mass materials (Mw > 12,000), and the relationship between their structure and properties has been carefully studied. Compared with conventional polyamides containing monodisperse PEO sequences, the polydispersity of the PEO segments within the structural units exerts a significant influence on the crystallinity, flexibility, solubility, and the thermal properties of the polymers. For instance, the all-para oriented polyamides (TPCP-A), with an average number of 8.2 ethylenoxide units per structural unit can be transformed conventionally (T(m) = 259 °C) in comparison with thermally untransformable polymer with 2 ethylenoxide units (T(m) = 425 °C). MDPI 2021-05-25 /pmc/articles/PMC8197558/ /pubmed/34070343 http://dx.doi.org/10.3390/ma14112804 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Trigo-López, Miriam Reglero Ruiz, José A. Peredo, Patricia D. Mendía, Aranzazu Muñoz, Asunción García, Félix C. García, José M. Segmented-Block Poly(ether amide)s Containing Flexible Polydisperse Polyethyleneoxide Sequences and Rigid Aromatic Amide Moieties |
title | Segmented-Block Poly(ether amide)s Containing Flexible Polydisperse Polyethyleneoxide Sequences and Rigid Aromatic Amide Moieties |
title_full | Segmented-Block Poly(ether amide)s Containing Flexible Polydisperse Polyethyleneoxide Sequences and Rigid Aromatic Amide Moieties |
title_fullStr | Segmented-Block Poly(ether amide)s Containing Flexible Polydisperse Polyethyleneoxide Sequences and Rigid Aromatic Amide Moieties |
title_full_unstemmed | Segmented-Block Poly(ether amide)s Containing Flexible Polydisperse Polyethyleneoxide Sequences and Rigid Aromatic Amide Moieties |
title_short | Segmented-Block Poly(ether amide)s Containing Flexible Polydisperse Polyethyleneoxide Sequences and Rigid Aromatic Amide Moieties |
title_sort | segmented-block poly(ether amide)s containing flexible polydisperse polyethyleneoxide sequences and rigid aromatic amide moieties |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8197558/ https://www.ncbi.nlm.nih.gov/pubmed/34070343 http://dx.doi.org/10.3390/ma14112804 |
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