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Multifunctional Leather Surface Design by Using Carbon Nanotube-Based Composites

This paper deals with original research in smart leather surface design for the development of multifunctional properties by using multi-walled carbon nanotube (MWCNT)-based nanocomposites. The conductive properties were demonstrated for both sheepskin and bovine leather surfaces for 0.5% MWCNTs in...

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Autores principales: Stanca, Maria, Gaidau, Carmen, Alexe, Cosmin-Andrei, Stanculescu, Ioana, Vasilca, Silvana, Matei, Andreea, Simion, Demetra, Constantinescu, Roxana-Rodica
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8199507/
https://www.ncbi.nlm.nih.gov/pubmed/34206068
http://dx.doi.org/10.3390/ma14113003
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author Stanca, Maria
Gaidau, Carmen
Alexe, Cosmin-Andrei
Stanculescu, Ioana
Vasilca, Silvana
Matei, Andreea
Simion, Demetra
Constantinescu, Roxana-Rodica
author_facet Stanca, Maria
Gaidau, Carmen
Alexe, Cosmin-Andrei
Stanculescu, Ioana
Vasilca, Silvana
Matei, Andreea
Simion, Demetra
Constantinescu, Roxana-Rodica
author_sort Stanca, Maria
collection PubMed
description This paper deals with original research in smart leather surface design for the development of multifunctional properties by using multi-walled carbon nanotube (MWCNT)-based nanocomposites. The conductive properties were demonstrated for both sheepskin and bovine leather surfaces for 0.5% MWCNTs in finishing nanocompositions with prospects for new material design intended for flexible electronics or multifunctional leathers. The photocatalytic properties of bovine leather surface treated with 0.5% MWCNTs were shown against an olive oil stain after visible light exposure and were attributed to reactive oxygen species generation and supported by contact angle measurements in dynamic conditions. The volatile organic compounds’ decomposition and antibacterial tests confirmed the self-cleaning experimental conclusions. Ultraviolet protection factor had excellent values for leather surfaces treated with multi-walled carbon nanotube and the fastness resistance tests showed improved performance compared to control samples. Scanning electron microscopy with energy dispersive X-ray (SEM-EDX), X-ray photoelectron spectroscopy (XPS), and attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy analysis confirmed the influence of different leather surfaces on MWCNT dispersion with an effect on nanoparticle reactivity and efficiency in self-cleaning properties. Multifunctional leather surfaces were designed and demonstrated through MWCNT-based nanocomposite use under conventional finishing conditions.
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spelling pubmed-81995072021-06-14 Multifunctional Leather Surface Design by Using Carbon Nanotube-Based Composites Stanca, Maria Gaidau, Carmen Alexe, Cosmin-Andrei Stanculescu, Ioana Vasilca, Silvana Matei, Andreea Simion, Demetra Constantinescu, Roxana-Rodica Materials (Basel) Article This paper deals with original research in smart leather surface design for the development of multifunctional properties by using multi-walled carbon nanotube (MWCNT)-based nanocomposites. The conductive properties were demonstrated for both sheepskin and bovine leather surfaces for 0.5% MWCNTs in finishing nanocompositions with prospects for new material design intended for flexible electronics or multifunctional leathers. The photocatalytic properties of bovine leather surface treated with 0.5% MWCNTs were shown against an olive oil stain after visible light exposure and were attributed to reactive oxygen species generation and supported by contact angle measurements in dynamic conditions. The volatile organic compounds’ decomposition and antibacterial tests confirmed the self-cleaning experimental conclusions. Ultraviolet protection factor had excellent values for leather surfaces treated with multi-walled carbon nanotube and the fastness resistance tests showed improved performance compared to control samples. Scanning electron microscopy with energy dispersive X-ray (SEM-EDX), X-ray photoelectron spectroscopy (XPS), and attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy analysis confirmed the influence of different leather surfaces on MWCNT dispersion with an effect on nanoparticle reactivity and efficiency in self-cleaning properties. Multifunctional leather surfaces were designed and demonstrated through MWCNT-based nanocomposite use under conventional finishing conditions. MDPI 2021-06-01 /pmc/articles/PMC8199507/ /pubmed/34206068 http://dx.doi.org/10.3390/ma14113003 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Stanca, Maria
Gaidau, Carmen
Alexe, Cosmin-Andrei
Stanculescu, Ioana
Vasilca, Silvana
Matei, Andreea
Simion, Demetra
Constantinescu, Roxana-Rodica
Multifunctional Leather Surface Design by Using Carbon Nanotube-Based Composites
title Multifunctional Leather Surface Design by Using Carbon Nanotube-Based Composites
title_full Multifunctional Leather Surface Design by Using Carbon Nanotube-Based Composites
title_fullStr Multifunctional Leather Surface Design by Using Carbon Nanotube-Based Composites
title_full_unstemmed Multifunctional Leather Surface Design by Using Carbon Nanotube-Based Composites
title_short Multifunctional Leather Surface Design by Using Carbon Nanotube-Based Composites
title_sort multifunctional leather surface design by using carbon nanotube-based composites
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8199507/
https://www.ncbi.nlm.nih.gov/pubmed/34206068
http://dx.doi.org/10.3390/ma14113003
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