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Construction of the Cellulose Nanofibers (CNFs) Aerogel Loading TiO(2) NPs and Its Application in Disposal of Organic Pollutants

Aerogels have been widely used in the adsorption of pollutants because of their large specific surface area. As an environmentally friendly natural polysaccharide, cellulose is a good candidate for the preparation of aerogels due to its wide sources and abundant polar groups. In this paper, an appro...

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Autores principales: Li, Kang, Zhang, Xuejie, Qin, Yan, Li, Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8199583/
https://www.ncbi.nlm.nih.gov/pubmed/34199425
http://dx.doi.org/10.3390/polym13111841
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author Li, Kang
Zhang, Xuejie
Qin, Yan
Li, Ying
author_facet Li, Kang
Zhang, Xuejie
Qin, Yan
Li, Ying
author_sort Li, Kang
collection PubMed
description Aerogels have been widely used in the adsorption of pollutants because of their large specific surface area. As an environmentally friendly natural polysaccharide, cellulose is a good candidate for the preparation of aerogels due to its wide sources and abundant polar groups. In this paper, an approach to construct cellulose nanofibers aerogels with both the good mechanical property and the high pollutants adsorption capability through chemical crosslinking was explored. On this basis, TiO(2) nanoparticles were loaded on the aerogel through the sol-gel method followed by the hydrothermal method, thereby the enriched pollutants in the aerogel could be degraded synchronously. The chemical cross-linker not only helps build the three-dimensional network structure of aerogels, but also provides loading sites for TiO(2). The degradation efficiency of pollutants by the TiO(2)@CNF Aerogel can reach more than 90% after 4 h, and the efficiency is still more than 70% after five cycles. The prepared TiO(2)@CNF Aerogels have high potential in the field of environmental management, because of the high efficiency of treating organic pollutes and the sustainability of the materials. The work also provides a choice for the functional utilization of cellulose, offering a valuable method to utilize the large amount of cellulose in nature.
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spelling pubmed-81995832021-06-14 Construction of the Cellulose Nanofibers (CNFs) Aerogel Loading TiO(2) NPs and Its Application in Disposal of Organic Pollutants Li, Kang Zhang, Xuejie Qin, Yan Li, Ying Polymers (Basel) Article Aerogels have been widely used in the adsorption of pollutants because of their large specific surface area. As an environmentally friendly natural polysaccharide, cellulose is a good candidate for the preparation of aerogels due to its wide sources and abundant polar groups. In this paper, an approach to construct cellulose nanofibers aerogels with both the good mechanical property and the high pollutants adsorption capability through chemical crosslinking was explored. On this basis, TiO(2) nanoparticles were loaded on the aerogel through the sol-gel method followed by the hydrothermal method, thereby the enriched pollutants in the aerogel could be degraded synchronously. The chemical cross-linker not only helps build the three-dimensional network structure of aerogels, but also provides loading sites for TiO(2). The degradation efficiency of pollutants by the TiO(2)@CNF Aerogel can reach more than 90% after 4 h, and the efficiency is still more than 70% after five cycles. The prepared TiO(2)@CNF Aerogels have high potential in the field of environmental management, because of the high efficiency of treating organic pollutes and the sustainability of the materials. The work also provides a choice for the functional utilization of cellulose, offering a valuable method to utilize the large amount of cellulose in nature. MDPI 2021-06-02 /pmc/articles/PMC8199583/ /pubmed/34199425 http://dx.doi.org/10.3390/polym13111841 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Li, Kang
Zhang, Xuejie
Qin, Yan
Li, Ying
Construction of the Cellulose Nanofibers (CNFs) Aerogel Loading TiO(2) NPs and Its Application in Disposal of Organic Pollutants
title Construction of the Cellulose Nanofibers (CNFs) Aerogel Loading TiO(2) NPs and Its Application in Disposal of Organic Pollutants
title_full Construction of the Cellulose Nanofibers (CNFs) Aerogel Loading TiO(2) NPs and Its Application in Disposal of Organic Pollutants
title_fullStr Construction of the Cellulose Nanofibers (CNFs) Aerogel Loading TiO(2) NPs and Its Application in Disposal of Organic Pollutants
title_full_unstemmed Construction of the Cellulose Nanofibers (CNFs) Aerogel Loading TiO(2) NPs and Its Application in Disposal of Organic Pollutants
title_short Construction of the Cellulose Nanofibers (CNFs) Aerogel Loading TiO(2) NPs and Its Application in Disposal of Organic Pollutants
title_sort construction of the cellulose nanofibers (cnfs) aerogel loading tio(2) nps and its application in disposal of organic pollutants
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8199583/
https://www.ncbi.nlm.nih.gov/pubmed/34199425
http://dx.doi.org/10.3390/polym13111841
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