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Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes

Carbazole derivatives are the structural key of many biologically active substances, including naturally occurring and synthetic ones. Three novel (E)-2-(2-(4-9H-carbazol-9-yl)benzylidene)hydrazinyl)triazole dyes were synthesized with different numbers of chlorine substituents attached at different...

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Autores principales: Krawczyk, Przemysław, Jędrzejewska, Beata, Seklecka, Klaudia, Cytarska, Joanna, Łączkowski, Krzysztof Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8200205/
https://www.ncbi.nlm.nih.gov/pubmed/34200060
http://dx.doi.org/10.3390/ma14113091
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author Krawczyk, Przemysław
Jędrzejewska, Beata
Seklecka, Klaudia
Cytarska, Joanna
Łączkowski, Krzysztof Z.
author_facet Krawczyk, Przemysław
Jędrzejewska, Beata
Seklecka, Klaudia
Cytarska, Joanna
Łączkowski, Krzysztof Z.
author_sort Krawczyk, Przemysław
collection PubMed
description Carbazole derivatives are the structural key of many biologically active substances, including naturally occurring and synthetic ones. Three novel (E)-2-(2-(4-9H-carbazol-9-yl)benzylidene)hydrazinyl)triazole dyes were synthesized with different numbers of chlorine substituents attached at different locations. The presented research has shown the influence of the number and position of attachment of chlorine substituents on electrochemical, optical, nonlinear, and biological properties. The study also included the analysis of the use of the presented derivatives as potential fluorescent probes for in vivo and in vitro tests. Quantum-chemical calculations complement the conducted experiments.
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spelling pubmed-82002052021-06-14 Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes Krawczyk, Przemysław Jędrzejewska, Beata Seklecka, Klaudia Cytarska, Joanna Łączkowski, Krzysztof Z. Materials (Basel) Article Carbazole derivatives are the structural key of many biologically active substances, including naturally occurring and synthetic ones. Three novel (E)-2-(2-(4-9H-carbazol-9-yl)benzylidene)hydrazinyl)triazole dyes were synthesized with different numbers of chlorine substituents attached at different locations. The presented research has shown the influence of the number and position of attachment of chlorine substituents on electrochemical, optical, nonlinear, and biological properties. The study also included the analysis of the use of the presented derivatives as potential fluorescent probes for in vivo and in vitro tests. Quantum-chemical calculations complement the conducted experiments. MDPI 2021-06-04 /pmc/articles/PMC8200205/ /pubmed/34200060 http://dx.doi.org/10.3390/ma14113091 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Krawczyk, Przemysław
Jędrzejewska, Beata
Seklecka, Klaudia
Cytarska, Joanna
Łączkowski, Krzysztof Z.
Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes
title Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes
title_full Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes
title_fullStr Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes
title_full_unstemmed Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes
title_short Effect of the Chloro-Substitution on Electrochemical and Optical Properties of New Carbazole Dyes
title_sort effect of the chloro-substitution on electrochemical and optical properties of new carbazole dyes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8200205/
https://www.ncbi.nlm.nih.gov/pubmed/34200060
http://dx.doi.org/10.3390/ma14113091
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